First- and second-order phase transitions in the adlayer of biadipate on Au(111)
| Data(s) |
2009
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|---|---|
| Resumo |
The adsorption of biadipate on Au(111) was studied by cyclic voltammetry and chronocoulometry. The biadipate adlayer undergoes a potential-driven phase transition. It is shown that the phase transition can be either of the first- or second-order depending on the biadipate concentration. At low surfactant concentrations, the first-order transition is characterised by a discontinuity in the charge density-potential curve and by the presence of very sharp peaks in the voltammetric response. At higher concentrations, these peaks are no longer observed but a discontinuity in the capacity curve is still noticeable, in agreement with a second-order transition. © the Owner Societies. SCOPUS: ar.j info:eu-repo/semantics/published |
| Formato |
1 full-text file(s): application/pdf |
| Identificador |
uri/info:doi/10.1039/b813883d uri/info:pmid/19835091 https://dipot.ulb.ac.be/dspace/bitstream/2013/93803/1/PCCP 2009.pdf http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/93803 |
| Idioma(s) |
en |
| Direitos |
1 full-text file(s): info:eu-repo/semantics/restrictedAccess |
| Fonte |
PCCP. Physical chemistry chemical physics, 11 (4 |
| Palavras-Chave | #Sciences exactes et naturelles |
| Tipo |
info:eu-repo/semantics/article info:ulb-repo/semantics/articlePeerReview info:ulb-repo/semantics/openurl/article |
