Functionalization of lamellar molybdenum disulphide nanocomposite with gold nanoparticles


Autoria(s): Lavayen, Vladimir; O'Dwyer, Colm; Santa-Ana, María A.; Mirabal, Neisy; Benavente, Eglantina; Cardenas, G.; Gonzalez, Guillermo; Sotomayor Torres, Clivia M.
Contribuinte(s)

Science Foundation Ireland

Universidad de Chile

Universidad Tecnológica Metropolitana, Chile

Fondo Nacional de Desarrollo Científico y Tecnológico, Chile

Data(s)

20/02/2013

20/02/2013

2007

01/01/2007

29/11/2012

Resumo

This work explores the functionalization of an organic-inorganic MoS2 lamellar compound, prepared by a Chemical Liquid Deposition Method (CLD), that has an interlamellar distance of ~5.2 nm, using clusters of gold nanoparticles. The gold nanoparticles have a mean diameter of 1.2 nm, a stability of ~85 days, and a zeta potential measured to be ζ = -6.8 mV (solid). The nanoparticles are localized in the hydrophilic zones, defined by the presence of amine groups of the surfactant between the lamella of MoS2. SEM, TEM, EDAX and electron diffraction provide conclusive evidence of the interlamellar insertion of the gold nanoparticles in the MoS2.

Fondo Nacional de Desarrollo Científico y Tecnológico, Chile (Grants 1050344, 1030102, 7050081); Science Foundation Ireland; PHOREMOST; Universidad de Chile

Accepted Version

Peer reviewed

Formato

application/pdf

Identificador

LAVAYEN, V., O’DWYER, C., ANA, M. A. S., MIRABAL, N., BENAVENTE, E., CÁRDENAS, G., GONZÁLEZ, G. & TORRES, C. M. S. (2007). Functionalization of lamellar molybdenum disulphide nanocomposite with gold nanoparticles. Applied Surface Science, 253, 3444-3449. http://dx.doi.org/10.1016/j.apsusc.2006.07.039

253

7

3444

3449

0169-4332

http://hdl.handle.net/10468/986

10.1016/j.apsusc.2006.07.039

Applied Surface Science

Idioma(s)

en

Publicador

Elsevier

Relação

http://www.sciencedirect.com/science/article/pii/S0169433206010051

Direitos

Copyright © 2007, Elsevier. NOTICE: this is the author’s version of a work that was accepted for publication in Applied Surface Science . Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Applied Surface Science [253, 7, 30 Jan 2007] DOI: http://dx.doi.org/10.1016/j.apsusc.2006.07.039

Palavras-Chave #Molybdenum #Colloid #Nanoparticles #Functionalization
Tipo

Article (peer-reviewed)