Tensor density matrix theory for determining population and alignment of symmetric top molecule using rotationally unresolved fluorescence
Data(s) |
10/02/2000
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Resumo |
General expressions used for transforming raw laser-induced fluorescence (LIF) intensity into the population and alignment parameters of a symmetric top molecule are derived by employing the density matrix approach. The molecular population and alignment are described by molecular state multipoles. The results are presented for a general excitation-detection geometry and then applied to some special geometries. In general cases, the LIF intensity is a complex function of the initial molecular state multipoles, the dynamic factors and the excitation-detection geometrical factors. It contains a population and 14 alignment multipoles. How to extract all initial state multipoles from the rotationally unresolved emission LIF intensity is discussed in detail. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
丛书林;韩克利;楼南泉.Tensor density matrix theory for determining population and alignment of symmetric top molecule using rotationally unresolved fluorescence,Molecular Physics,2000,3(98):139-147 |
Tipo |
期刊论文 |