THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu vertical bar CuSO4 vertical bar Hg2SO4-Hg AT DIFFERENT TEMPERATURES


Autoria(s): Cheng ZH; Li H; Zhang LTA; Yang JZ; Liang CY
Data(s)

1989

Resumo

The emfs of Cu|CuSO_4|Hg_2SO_4-Hg were determined at 5 temperature points from 278.15K to 313.15K. Based on the Pitzer' s Equation a polynomial approximation for the determination of standard emf, E_m, was proposed. The values of E_m obtained by author's method agree with values of E_m obtained by the extended Debye-Huckel equation within experimental errors. Compared with the extrapolation result of extended Debye-Huckel equation, the uncertainty by the selecting of parameter of ion size was avoided.By the...

Identificador

http://202.98.16.49/handle/322003/40557

http://www.irgrid.ac.cn/handle/1471x/164652

Idioma(s)

中文

Fonte

Cheng ZH;Li H;Zhang LTA;Yang JZ;Liang CY.THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu vertical bar CuSO4 vertical bar Hg2SO4-Hg AT DIFFERENT TEMPERATURES,ACTA PHYSICO-CHIMICA SINICA,1989,5(5):590-593

Tipo

期刊论文