THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu vertical bar CuSO4 vertical bar Hg2SO4-Hg AT DIFFERENT TEMPERATURES
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1989
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Resumo |
The emfs of Cu|CuSO_4|Hg_2SO_4-Hg were determined at 5 temperature points from 278.15K to 313.15K. Based on the Pitzer' s Equation a polynomial approximation for the determination of standard emf, E_m, was proposed. The values of E_m obtained by author's method agree with values of E_m obtained by the extended Debye-Huckel equation within experimental errors. Compared with the extrapolation result of extended Debye-Huckel equation, the uncertainty by the selecting of parameter of ion size was avoided.By the... |
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Idioma(s) |
中文 |
Fonte |
Cheng ZH;Li H;Zhang LTA;Yang JZ;Liang CY.THE DETERMINATION OF STANDARD ELECTROMOTIVE FORCE OF CELL Cu vertical bar CuSO4 vertical bar Hg2SO4-Hg AT DIFFERENT TEMPERATURES,ACTA PHYSICO-CHIMICA SINICA,1989,5(5):590-593 |
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期刊论文 |