RADIATION-INDUCED CROSS-LINKING OF AROMATIC POLYMERS WITH A CARDO GROUP

The effects of irradiation on some members of the family of aromatic polymers with a cardo group, such as polyetherketone with a cardo group (PEK-C) and polyethersulfone with a cardo group (PES-C), were studied. It was found that PEK-C and PES-C can be crosslinked by irradiation under vacuum. Moreover, it was also found that the intensity of the shake-up peak of x-ray photoelectron spectroscopy (XPS) for PEK-C and PES-C varies with irradiation dose. Gelation doses (Rg) of PEK-C and PES-C were estimated from the XPS shake-up peak.