RADIATION STABILITY OF PTFE WITH DIFFERENT CRYSTALLINITY

In this work, the effects of radiation on polytetrafluoroethylene (PTFE) samples with different crystallinity were studied. Using Suwa's equation for calculating the number-average molecular weight of PTFE, the radiation-induced reduction in molecular weight was followed and the G values for scission of PTFE were also obtained on the basis of the changes in molecular weight. The G(scission) for as-polymerized PTFE was 2.15 +/- 0.01, whereas for sintered sample, which has a relative low crystallinity, G(scission) = 6.0 +/- 0.14.