STUDIES ON THE REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES .6. REACTION OF CP2ZR(H)CL WITH RNCS (R=C6H5, 2-C10H7, C-C6H11 AND N-C4H9)
| Data(s) |
1993
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| Resumo |
The novel NS-containing zirconacycle complexes Cp2ZrCl[SC(H)NR] (1a, R = C6H5; 1b, R = 2-C10H7; 1c, R= C-C6H11; 1d; R = n-C4H9) were obtained by insertion reactions of Cp2Zr(H)Cl with RNCS. 1(a-d) could react further with Cp2Zr(H)Cl to yield a sulphur-bridging compleX (Cp2ZrCl)2S (2) and a Schiff base RN=CH2. The crystal structure of la has been determined by X-ray analysis. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
WANG M;LU SW;BEI MZ;GUO HF;JIN ZS.STUDIES ON THE REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES .6. REACTION OF CP2ZR(H)CL WITH RNCS (R=C6H5, 2-C10H7, C-C6H11 AND N-C4H9),JOURNAL OF ORGANOMETALLIC CHEMISTRY,1993,447(2):227-231 |
| Palavras-Chave | #ESTER COMPLEX <PH2PCH2CH2N(CH2CH2PPH2)2NI(CS2ME)>BPH4 #PLATINUM METALS #CO2-LIKE MOLECULES #DERIVATIVES #RUTHENIUM #IRIDIUM #OSMIUM #<N(CH2CH2PPH2)3>NI #ZIRCONIUM #SCNPH |
| Tipo |
期刊论文 |
