SYNTHESIS AND CHARACTERIZATION OF HETEROPOLY BLUES OF BIS-2/17 MOLYBDOPHOSPHATE COMPLEXES WITH LANTHANIDE
Data(s) |
1993
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Resumo |
Eight heteropoly blues of bis-2:17 molybdophosphate complexes with Lathanide, i.e., K17H2[Ln(P2Mo17O61)2] . nH2O and K17H4[Ln(P2Mo17O61)2] . nH2O were synthesized and characterized by elemental analyses potentiometric titration, IR, UV, polarography, cyclic voltammetry, X-ray photoelectron spectra X-ray powder diffraction, thermal analyses and ESR. Experimental results show that the properties of these series of heteropoly blues are different from those of their oxidized form, but no great changes in their structures were observed. The ligand P2Mo17O6110- remains alpha2-isomer's configuration. |
Identificador | |
Idioma(s) |
中文 |
Fonte |
WANG EB;ZHANG LC;WANG ZP;HUANG RD;ZHANG BJ;ZHAN RY;LIU YY.SYNTHESIS AND CHARACTERIZATION OF HETEROPOLY BLUES OF BIS-2/17 MOLYBDOPHOSPHATE COMPLEXES WITH LANTHANIDE,ACTA CHIMICA SINICA,1993,51(4):352-357 |
Tipo |
期刊论文 |