Crystal and molecular structure of the complex of methoxycarbonylethyltin trichloride with salicylidene-m-toluidine
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1995
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Resumo |
The synthesis and properties of the title complex CH3OCOCH2CH2SnCl3.2-HOC6H4CH=NC6H4-3'-CH3 are described. It crystallizes from benzene in the monoclinic space group P2(1/n) with unit cell dimensions a=10.326 (C),b=6.815(8), c=12.931(6) Angstrom, beta =111.52(3,)degrees, V=2088.7(1) Angstrom (3), Z=4, F(000) =1040, mu =16.31 cm(-1), Dc=1. 67g/cm(3) final R factor is 0.037 for 3177 observed reflections, 1 greater than or equal to3 sigma (1(0)). The tin atom in the structure of the complex exists in a distored octahedral geometry defined by three Cl atoms, the C and O atoms of a chelating methoxycarbonylethyl. group as well as an O atom derived from the Schiff base ligand. |
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Idioma(s) |
英语 |
Fonte |
Fu FX;Li XJ;De Pan H;Xing Y;Lin YH.Crystal and molecular structure of the complex of methoxycarbonylethyltin trichloride with salicylidene-m-toluidine,CHINESE CHEMICAL LETTERS,1995,6(1):87-90 |
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期刊论文 |