A study of the radical reaction of C-60 with n-Bu(3)SnH
Data(s) |
1996
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Resumo |
The reaction of buckministerfullerene (C-60) with tri-n-blltyltin hydride(n-Bu(3)SnH) in toluene solution has been investigated. According to mass spectrometry analysis, the products of above reaction are C-60(BuH)(n)(n = 1 similar to 3) and Bu(x)Sn(y)H(x) (x = 3 similar to 8, y = 1 similar to 4,approximate to = 0 similar to 3). The reaction maybe provide a new method for the synthesis of alkylated fullerene derivatives. Where C-60 also takes a role of a catalysis of organtic-tin polymerization. The radical reaction mechanism has been discussed. |
Identificador | |
Idioma(s) |
中文 |
Fonte |
She YM;Guo XH;Liu ZY;Liu SY;Fu FX;Qian MX.A study of the radical reaction of C-60 with n-Bu(3)SnH,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1996,17(2):303-305 |
Palavras-Chave | #CHEMISTRY #C60 |
Tipo |
期刊论文 |