Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt(4)](3)[Mo2Fe6S8(mu-OMe)(3)(SPh)(3)Cl-3]
| Data(s) |
1996
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|---|---|
| Resumo |
The new double-cubane cluster compound [NEt(4)](3)[Mo2Fe6S8(mu-OMe)(3)(SPh)(3)Cl-3] is synthesized from (NH4)(2)MoS4, FeCl3, Fe powder, S powder, NaSPh and NEt(4)Br in MeOH-DMF, its crystal structure is determined by X-ray crystallography, and results of XPS indicate a valence state of +4 for Mo. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Xu JQ;Zhang XG;Cai H;Hu NH;Wei CP;Yang GY;Wang TG.Synthesis and characterization of a new double-cubane Mo-Fe-S cluster compound, [NEt(4)](3)[Mo2Fe6S8(mu-OMe)(3)(SPh)(3)Cl-3],CHEMICAL COMMUNICATIONS,1996,(6):757-758 |
| Palavras-Chave | #MOLYBDENUM-IRON PROTEIN #CLOSTRIDIUM-PASTEURIANUM #STRUCTURAL FEATURES #MOFE3S4 CUBANES #METAL-CLUSTERS #NITROGENASE #SITE #RESOLUTION #ANALOGS #MODELS |
| Tipo |
期刊论文 |
