C-13 NMR study on the aqueous structure of lanthanide citrate complexes

The aqueous complexation of lanthanide complexes of citrate in pH 7.4 solutions has been studied by using lanthanide-induced shift and relaxation times measurement methods. These results indicate that citrate coordinate via 3-hydroxyl and 3-carboxylate groups with lanthanide ions and form 1:2 (Ln/cit) isostructural complexes through lanthanide series. We suggest a new coordination geometry which is different from that described in literature.