Gas Phase Addition of Rare-earth Fullerenes with Benzene
Data(s) |
1997
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Resumo |
Gas phase adduct of endohedral rare-earth fullerenes Nd@C-S2 with the ion system of benzene-[Nd@C-S2-C6H6](+) was observed for the first time by ion-molecular reaction under chemical ionization condition. The possible reaction passageway and molecular structures of this gas phase adduct were discussed and a parallel "reversed umbrella" pi-pi interaction complex of the [C6H6](+) ion reacting with the neutral rare-earth fullerenes Nd@C-S2 was considered to be much reasonable. The experimental result indicated that endohedral rare-earth fullerenes has relatively active reactivity and aromatic properties similar towards benzene molecular ion in gas phase. |
Identificador | |
Idioma(s) |
中文 |
Fonte |
Sun DY;Liu ZY;Xu WG;Guo XH;Liu SY.Gas Phase Addition of Rare-earth Fullerenes with Benzene,ACTA PHYSICO-CHIMICA SINICA,1997,13(10):929-932 |
Tipo |
期刊论文 |