Synthesis, properties and crystal structure of a heteropoly compound containing titanium
| Data(s) |
1997
|
|---|---|
| Resumo |
K4H2CoW12O40. 2Ti02 . 9H(2)O crystallizes from an aqueous solution of Na2WO4, Co(OAc)(2) and Ti(SO4)(2). The compound has very similar i.r. and u.v. spectra to those of [CoW12O40](6-) and [CoW11TiO40](8-) but its polarographic behaviour is different from that of [CoW11TiO40](8-) and exhibits only reduction of tungsten(VI). A single crystal structural analysis indicates that this compound consists of the heteropolyanion [CoW12O40](6-), titanium-oxygen chain, potassium ions and water molecules. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Chen YG;Liu JF;Xing Y;Lin YH;Jia HQ;Bai SY.Synthesis, properties and crystal structure of a heteropoly compound containing titanium,TRANSITION METAL CHEMISTRY,1997,22(4):356-359 |
| Tipo |
期刊论文 |
