Reaction of halfsandwich iridium polychalcogenide complexes with dimethyl acetylenedicarboxylate. Molecular structure of Cp*Ir[S2C2(COOMe)(2)]
| Data(s) |
1998
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|---|---|
| Resumo |
The pentamethylcyclopentadienyl iridium complexes Cp*Ir(PMe3)(E-n) (E = S, n = 4, 5 or 6; E = Se, n = 2 or 4 E = Te, n = 2) react with dimethyl acetylenedicarboxylate to give Cp*Ir(PMe3)[E2C2(COOMe)(2)] compounds which tend to lose the trimethylphosphine ligand; the molecular structure of the dithiolene derivative, Cp*Ir[S2C2(COOMe)(2)], has been determined. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Jin GX;Herberhold M;Reingold AL.Reaction of halfsandwich iridium polychalcogenide complexes with dimethyl acetylenedicarboxylate. Molecular structure of Cp*Ir[S2C2(COOMe)(2)],NEW JOURNAL OF CHEMISTRY,1998,22(10):1035-1036 |
| Palavras-Chave | #S2(2-) = 1 #TRANSITION-METAL COMPLEXES #ELEMENTAL SULFUR #LIGANDS #COORDINATION #ADDUCT #2-BENZENEDITHIOLATE(2-) |
| Tipo |
期刊论文 |
