Synthesis and x-ray structure of a highly symmetrical selenium-centered hexanuclear neodymium complex, [(Cp6Nd6Se13)-Nd-t](-) (Cp-t=eta(5)-(BuC5H4)-C-t)
| Data(s) |
1999
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|---|---|
| Resumo |
The half-sandwich tert-buthylcyclopentadienyl neodymium complex [(CpNdCl2)-Nd-t(THF)(2)](2) (1) reacts with Na2Se5 to give organoneodymium polyselenide complex [Na(THF)(6)][(Cp6Nd6)-Nd-t(mu(6)-Se)(mu(2)-Se-2)(6)] (2) which has been characterized by X-ray crystallography. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Jin GX;Cheng YX;Lin YH.Synthesis and x-ray structure of a highly symmetrical selenium-centered hexanuclear neodymium complex, [(Cp6Nd6Se13)-Nd-t](-) (Cp-t=eta(5)-(BuC5H4)-C-t),ORGANOMETALLICS,1999,18(6):947-949 |
| Palavras-Chave | #PENTAMETHYLCYCLOPENTADIENYL IRIDIUM COMPLEXES #CHALCOGENIDO LIGANDS #CRYSTAL-STRUCTURE #SULFUR #CYCLOPENTADIENYL #REACTIVITY #CHEMISTRY #SULFIDO #ANIONS #RICH |
| Tipo |
期刊论文 |
