The development in oxidation of olefins to ketones catalyzed by palladium compounds


Autoria(s): Li HM; Shu HM; Ye XK; Wu Y
Data(s)

2001

Resumo

The development in the oxidation of olefins to ketones catalyzed by palladium compounds was reviewed. Some improved methods for the oxidation of olefins catalyzed by Wacker-type catalyst systems are also summarized. For this reaction, some new catalyst systems and the reaction mechanism are described. Emphasis has been given to the applications of Pd(I)/HPA(heteropoly acid), Pd(I)/FePc (iron phthalocyanine), Pd (I)/HQ (hydroquinone)/FePc, Pd (I)/HQ/HPA, Pd (I)/CuSO4/HPA catalyst systems in the oxidation of olefins to ketones; the application of Pd(I)/LCoNO2, PdCl2 (MeCN)(2)/CuCl, Pd(OAc)(2)/ pyridine, fluorous biphasic catalyst systems in the oxidation of olefins to ketones is also surveyed.

Identificador

http://ir.ciac.jl.cn/handle/322003/20459

http://www.irgrid.ac.cn/handle/1471x/154964

Idioma(s)

中文

Fonte

Li HM;Shu HM;Ye XK;Wu Y.The development in oxidation of olefins to ketones catalyzed by palladium compounds,PROGRESS IN CHEMISTRY,2001,13(6):461-471

Palavras-Chave #WACKER-TYPE CATALYSTS #PHASE-TRANSFER CATALYSIS #SUPPORTED AQUEOUS-PHASE #HOST-GUEST CHEMISTRY #MOLECULAR-OXYGEN #PALLADIUM(II)-CATALYZED OXIDATION #INTERNAL OLEFINS #HETEROPOLY ACIDS #METHYL KETONES #LIQUID-PHASE
Tipo

期刊论文