Synthesis, structure characterization and biological activity of a novel amino acid salt (HAla)(8)(H3O)(10)[PMo12O40](6) center dot 22H(2)O


Autoria(s): Han ZB; Wang EB; Luan GY; Hu CW; Chang YP; Li J; Hu NH; Jia HQ
Data(s)

2001

Resumo

A novel compound was synthesized and characterized by means of elemental analysis, IR and UV spectra, TG, CV and single crystal X-ray diffraction. The compound crystallized in an orthorhombic space group C222 with a=1. 622 4(3) nm, b=3. 498 4(7) nm, c=1. 301 5(3) nm, V=7. 387 (3) nm(3), Z=6, R-1= 0. 037 3, wR(2)=0. 114 0. The Ala (Ala = alanine) molecules were protonated at the amino nitrogen N (1) and the C (2) of Ala group with the terminal oxygen atom O(15), O(14), O(26) and O(27) of the polyoxometalates participating in the hydrogen bond network. The anti-tumor activity of the title compound was estimated against Hela and Pc-3m cancer cells.

Identificador

http://202.98.16.49/handle/322003/20453

http://www.irgrid.ac.cn/handle/1471x/154961

Idioma(s)

英语

Fonte

Han ZB;Wang EB;Luan GY;Hu CW;Chang YP;Li J;Hu NH;Jia HQ.Synthesis, structure characterization and biological activity of a novel amino acid salt (HAla)(8)(H3O)(10)[PMo12O40](6) center dot 22H(2)O,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2001,17(4):356-361

Palavras-Chave #CRYSTAL-STRUCTURE #POLYOXOMETALATE #COMPLEX
Tipo

期刊论文