Synthesis, structure characterization and biological activity of a novel amino acid salt (HAla)(8)(H3O)(10)[PMo12O40](6) center dot 22H(2)O
Data(s) |
2001
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Resumo |
A novel compound was synthesized and characterized by means of elemental analysis, IR and UV spectra, TG, CV and single crystal X-ray diffraction. The compound crystallized in an orthorhombic space group C222 with a=1. 622 4(3) nm, b=3. 498 4(7) nm, c=1. 301 5(3) nm, V=7. 387 (3) nm(3), Z=6, R-1= 0. 037 3, wR(2)=0. 114 0. The Ala (Ala = alanine) molecules were protonated at the amino nitrogen N (1) and the C (2) of Ala group with the terminal oxygen atom O(15), O(14), O(26) and O(27) of the polyoxometalates participating in the hydrogen bond network. The anti-tumor activity of the title compound was estimated against Hela and Pc-3m cancer cells. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Han ZB;Wang EB;Luan GY;Hu CW;Chang YP;Li J;Hu NH;Jia HQ.Synthesis, structure characterization and biological activity of a novel amino acid salt (HAla)(8)(H3O)(10)[PMo12O40](6) center dot 22H(2)O,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2001,17(4):356-361 |
Palavras-Chave | #CRYSTAL-STRUCTURE #POLYOXOMETALATE #COMPLEX |
Tipo |
期刊论文 |