Sol-gel-derived, polishable, 1 : 12-phosphomolybdic acid-modified ceramic-carbon electrode and its electrocatalytic oxidation of ascorbic acid
Data(s) |
2000
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Resumo |
Novel ceramic-carbon electrodes (CCEs) containing 1:12-phosphomolybdic acid (PMo12) were constructed by homogeneously dispersing PMo12 and graphite powder into methyltrimethoxysilane-derived gel. Peak currents for the PMo12-doped CCE were surface-controlled at lower scan rates but diffusion-controlled at higher scan rates and peak potentials shifted to the negative potential direction with increasing pH. In addition, the electrode exhibited electrocatalytic activity toward the oxidation of ascorbic acid. The PMo12-modified CCE presented good chemical and mechanical stability and good surface renewability (ten successive polishing resulted in less than 5% relative standard deviation). (C) 2000 Elsevier Science B.V. All rights reserved. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Wang P;Wang XP;Jing XY;Zhu GY.Sol-gel-derived, polishable, 1 : 12-phosphomolybdic acid-modified ceramic-carbon electrode and its electrocatalytic oxidation of ascorbic acid,ANALYTICA CHIMICA ACTA,2000,424(1):51-56 |
Palavras-Chave | #FILM-MODIFIED MICROELECTRODES #1/12 PHOSPHOMOLYBDIC ANIONS #12-MOLYBDOPHOSPHORIC ACID #ELECTROCHEMICAL-BEHAVIOR #MULTILAYER FILMS #GLUCOSE-OXIDASE #COMPOSITE #FABRICATION #CHEMISTRY #SURFACE |
Tipo |
期刊论文 |