Hydrothermal synthesis, structure, and characterization of two one-dimensional chainlike hybrid complexes [(CuX)(2)(o-phen)](infinity) (X = Br, Cl; o-phen = o-phenanthroline)


Autoria(s): Wang ST; Wang EB; Hou Y; Li YG; Yuan M; Hu NH
Data(s)

2003

Resumo

Two novel organic-inorganic hybrid complexes [(CuX)(2)(o-phen)](infinity) (X = Br (1), Cl (2); o-phen = o-phenanthroline) have been synthesized hydrothermally and characterized structurally by elemental analyses, IR, ESR, XPS spectrum, TG analyses and single-crystal X-ray diffraction. Both title compounds exhibit novel one-dimensional chainlike copper halide scaffolding constructed by the unusual [Cu3X3] hexagon motifs by sharing opposite edges, where a single Cu site of each [Cu3X3] hexagon is chelated with N donors of o-phen group. To our knowledge, such basic o-phen-copper halide skeleton has not been reported hitherto. Moreover, TG analyses indicate that both title compounds possess high thermal stability.

Identificador

http://ir.ciac.jl.cn/handle/322003/17575

http://www.irgrid.ac.cn/handle/1471x/153104

Idioma(s)

英语

Fonte

Wang ST;Wang EB;Hou Y;Li YG;Yuan M;Hu NH.Hydrothermal synthesis, structure, and characterization of two one-dimensional chainlike hybrid complexes [(CuX)(2)(o-phen)](infinity) (X = Br, Cl; o-phen = o-phenanthroline),INORGANICA CHIMICA ACTA,2003,349():123-127

Palavras-Chave #CRYSTAL-STRUCTURE #COORDINATION POLYMERS #MAGNETIC-SUSCEPTIBILITY #HALIDE SALTS #SYSTEM #CHANNELS #CHLORIDE
Tipo

期刊论文