Synthesis, characterization and crystal structure of a new layered heterometallic coordination polymer {[(CuL) Sr-2(H2O)center dot Sr-2(H2O)(7)]center dot 2H(2)O center dot 0.5CH(3)OH}(n)


Autoria(s): Tao RJ; Liu BL; Li FA; Cheng YX; Niu JY
Data(s)

2006

Resumo

A copper-strontium heterometallic coordination polymer was synthesized and characterized by elemental analysis and IR spectra. The crystal structure was determined by single-crystal X-ray diffraction analyses. The title complex is a 2 D coordination polymer with the chemical formula [[(CuL)(2)Sr (H2O) center dot Sr-2 ((HO)-O-2)(7)]center dot 2H(2)O center dot 0.5CH(3)OH](n), where H4L = N-(2-hydroxybenzamido)-N'-(3-carboxylsalicylidene) ethylenediamine. Its structural unit is comprised of two adjacent units, which polymerized with each other to form a new layered heterometallic coordination polymer.

Identificador

http://ir.ciac.jl.cn/handle/322003/16865

http://www.irgrid.ac.cn/handle/1471x/152576

Idioma(s)

中文

Fonte

Tao RJ;Liu BL;Li FA;Cheng YX;Niu JY.Synthesis, characterization and crystal structure of a new layered heterometallic coordination polymer {[(CuL) Sr-2(H2O)center dot Sr-2(H2O)(7)]center dot 2H(2)O center dot 0.5CH(3)OH}(n),CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(8):1400-1403

Palavras-Chave #DISSYMMETRICAL MONONUCLEAR ENTITIES #MAGNETIC-PROPERTIES #TETRANUCLEAR COMPLEXES #SCHIFF-BASE #HEXAFLUOROACETYLACETONE #HHFAC
Tipo

期刊论文