Syntheses, structures and luminescence of silver(I) sulfonate complexes with PPh3 ligand


Autoria(s): Li FF; Ma HF; Yang J; Jia HQ; Hu NH
Data(s)

2006

Resumo

In this paper, four new luminescent silver(I) sulfonate complexes with PPh3, namely Ag(L1)(PPh3)(2) (1), Ag(L2)(PPh3)(3) (2), [Ag-2(L3)(PPh3)(4) (H2O)center dot 1.5CH(3)CN center dot 0.5H(2)O (3) and [Ag-4(L4)(PPh3)(10)]center dot 8H(2)O (4), where L1=p-toluenesulfonate, L2=1-naphthalenesulfonate, L3=3-carboxylate-4-hydroxybenzenesulfonate, L4=1, 3, 6, 8-pyrenetetrasulfonatc and PPh3=triphenylphosphine, have been synthesized and characterized. The crystal structures were determined by single-crystal X-ray diffraction method. Compounds 1, 2, 3 and 4 adopt discrete structures rather than polymeric structures. Compounds I and 2 show mononuclear structures while 3 and 4 are dinuclear and tetranuclear molecules, respectively. Moreover the numbers of PPh3 molecules coordinating to one silver center are two or three. The photoluminescent properties of 1, 2 and 3 are discussed.

Identificador

http://ir.ciac.jl.cn/handle/322003/16535

http://www.irgrid.ac.cn/handle/1471x/152248

Idioma(s)

英语

Fonte

Li FF;Ma HF;Yang J;Jia HQ;Hu NH.Syntheses, structures and luminescence of silver(I) sulfonate complexes with PPh3 ligand,JOURNAL OF MOLECULAR STRUCTURE,2006,787(1-3):106-112

Palavras-Chave #CRYSTAL-STRUCTURE #SOLID-STATE #X-RAY #COORDINATION #REACTIVITY #POLYMERS
Tipo

期刊论文