Synthesis, crystal structure, and photoluminescent property of a novel heterobimetallic Zn(II)-Ag(I) cyano-bridged coordination polymer incorporating,a pentameric unit [Ag(CN)(2-)](5) assembled by argentophilic interaction


Autoria(s): Zhang H; Zhang YJ; Wang C; Cai LR; Xie YT; Xue GQ
Data(s)

2006

Resumo

A new photoluminescent heterobimetallic Zn(II)-Ag(I) cyano-bridged coordination polymer, [Ag5Zn2(tren)(2)(CN)(9)] (tren = tris(2-aminoethyl)amine) (1), has been synthesized and structurally characterized. It features rare linear pentameric unit of dicyanoargentate(I) ions assembled by d(10)-d(10) interaction as building blocks. Solid state emission spectrum of I shows strong ultraviolet luminescence with emission peak in the range of 376 nm.

Identificador

http://ir.ciac.jl.cn/handle/322003/16439

http://www.irgrid.ac.cn/handle/1471x/152155

Idioma(s)

英语

Fonte

Zhang H;Zhang YJ;Wang C;Cai LR;Xie YT;Xue GQ.Synthesis, crystal structure, and photoluminescent property of a novel heterobimetallic Zn(II)-Ag(I) cyano-bridged coordination polymer incorporating,a pentameric unit [Ag(CN)(2-)](5) assembled by argentophilic interaction,INORGANIC CHEMISTRY COMMUNICATIONS,2006,9(5):555-558

Palavras-Chave #METAL-METAL INTERACTIONS #LUMINESCENT HOMOATOMIC EXCIPLEXES #SITE-SELECTIVE EXCITATION #ALKALI-HALIDE CRYSTALS #COMPLEXES #IONS #AG
Tipo

期刊论文