Bronsted guanidine acid-base ionic liquids: Novel reaction media for the palladium-catalyzed Heck reaction
| Data(s) |
2006
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|---|---|
| Resumo |
Bronsted acid-base ionic liquids (GILs) based on guanidine and acetic acid are efficient reaction media for palladium-catalyzed Heck reactions. They offer the advantages of high activity and reusability. GIL2 plays multiple roles in the reaction: it could act as solvent, as a strong base to facilitate beta-hydride elimination, and as a ligand to stabilize activated Pd species. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Li SH;Lin YJ;Xie HB;Zhang SB;Xu JN.Bronsted guanidine acid-base ionic liquids: Novel reaction media for the palladium-catalyzed Heck reaction,ORGANIC LETTERS,2006,8(3):391-394 |
| Palavras-Chave | #HIGHLY EFFICIENT #COUPLING REACTIONS #HETEROGENEOUS CATALYSTS #CARBENE COMPLEXES #ORGANIC-SYNTHESIS #MODIFIED ZEOLITES #PD NANOPARTICLES #MOLECULAR-SIEVES #ACTIVE CATALYST #ARYL CHLORIDES |
| Tipo |
期刊论文 |
