A new route to control product selectivity in the oxidative dehydrogenation of cyclohexane and cyclohexene
| Data(s) |
2004
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|---|---|
| Resumo |
The product selectivity can be controlled by adding acetic acid in feed over vanadium phosphate (VPO) in gas phase oxidative dehydrogenation (ODH), in which cyclohexane and cyclohexene are oxidized to cyclohexene and 1,3-cyclohexadiene (1,3-CHD), respectively, at almost 100% selectivity. This approach is also an efficient method to capture the very unstable intermediates in the mechanism study. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Zhu YJ;Li J;Yang XG;Wu Y.A new route to control product selectivity in the oxidative dehydrogenation of cyclohexane and cyclohexene,CHEMISTRY LETTERS,2004,33(7):822-823 |
| Palavras-Chave | #SUM-FREQUENCY GENERATION #ADIPIC ACID #VIBRATIONAL SPECTROSCOPY #CATALYST #1 #HYDROGENATION #MECHANISM #BUTADIENE #PARAFFINS #BENZENE #3-CYCLOHEXADIENE |
| Tipo |
期刊论文 |
