An ionic liquid based on a cyclic guanidinium cation is an efficient medium for the selective oxidation of benzyl alcohols
| Data(s) |
2004
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|---|---|
| Resumo |
A novel room temperature ionic liquid (RTIL) has been prepared containing a cyclic hexaalkylguanidinium cation. The selective oxidation of a series of substituted benzyl alcohols has been carried out in it, with sodium hypochlorite as the oxidant. The RTIL acts as both phase transfer catalyst (PTC) and solvent. The ionic liquid could be recycled after extraction of the benzaldehyde product with ether. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Xie HB;Zhang SB;Duan HF.An ionic liquid based on a cyclic guanidinium cation is an efficient medium for the selective oxidation of benzyl alcohols,TETRAHEDRON LETTERS ,2004,45(9 ):2013-2015 |
| Palavras-Chave | #TRANSFER CATALYTIC-SYSTEMS #AEROBIC OXIDATION #PALLADIUM(II)-CATALYZED OXIDATION #RUTHENIUM CATALYSTS #SODIUM-HYPOCHLORITE #MOLECULAR-OXYGEN #ALDEHYDES #KETONES #HYDROGENATION #COMPLEXES |
| Tipo |
期刊论文 |
