A single ionic conductor based on Nafion and its electrochemical properties used as lithium polymer electrolyte
Data(s) |
2004
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Resumo |
In an attempt to raise the transport number of Li+ to nearly unity in solid polymer electrolytes, commercial perfluorinated sulfonate acid membrane Nafion 117 was lithiated and codissolved with copolymer poly(vinylidene fluoride)hexafluoropropylene. The effect of fumed silica on the physical and electrochemical properties of the single ion conduction polymer electrolyte was studied with atom force microscopy, fourier transform infrared spectroscopy, differential scanning calorimetry, and electrochemical impedance spectroscopy. It was confirmed that the fumed silica has an obvious effect on the morphology of polymer electrolyte membranes and ionic conductivity. The resulting materials exhibit good film formation, solvent-maintaining capability, and dimensional stability. The lithium polymer electrolyte after gelling with a plasticizer shows a high ionic conductivity of 3.18 x 10(-4) S/cm. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Wang MK;Zhao F;Dong SJ.A single ionic conductor based on Nafion and its electrochemical properties used as lithium polymer electrolyte,JOURNAL OF PHYSICAL CHEMISTRY B ,2004,108(4):1365-1370 |
Palavras-Chave | #POLY(ETHYLENE OXIDE) #GEL ELECTROLYTES #POLY(VINYLIDENE FLUORIDE) #COMPOSITE ELECTROLYTES #BLOCKING ELECTRODES #FUMED SILICA #PVDF-HFP #BATTERIES #IMPEDANCE #SPECTROSCOPY |
Tipo |
期刊论文 |