The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis, structure and characterization of [V16O38(Cl)](8-)


Autoria(s): Chen YH; Gu XJ; Peng J; Shi ZY; Yu HQ; Wang E; Hu NH
Data(s)

2004

Resumo

A new compound, [NH4](2)[Zn(phen)(3)](2)[Zn(phen)(2)(H2O)(2)][V16O38(Cl)] (.) 5H(2)O (1), was synthesized in the hydrothermal condition. The "naked" [V16O38(Cl)](8-) is the first observation with host shell structure in polyoxovanadate chemistry.

Identificador

http://ir.ciac.jl.cn/handle/322003/14899

http://www.irgrid.ac.cn/handle/1471x/150648

Idioma(s)

英语

Fonte

Chen YH;Gu XJ;Peng J;Shi ZY;Yu HQ;Wang E;Hu NH.The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis, structure and characterization of [V16O38(Cl)](8-),INORGANIC CHEMISTRY COMMUNICATIONS,2004,7(5):705-707

Palavras-Chave #OPEN-AND-SHUT
Tipo

期刊论文