C-H activation motivated by N,N '-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand
| Data(s) |
2007
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|---|---|
| Resumo |
A lutetium bis( alkyl) complex stabilized by a flexible amino phosphine ligand LLu( CH2Si(CH3)(3))(2)(THF) (L = (2,6-C6H3( CH3)(2)) NCH( C6H5) CH2P(C6H5)(2)) was prepared which upon insertion of N, N'-diisopropylcarbodiimide led to C-H activation via metalation of the ligand aryl methyl followed by reduction of the C=N double bond. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Liu B;Yang Y;Cui DM;Tang T;Chen XS;Jing XB.C-H activation motivated by N,N '-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand,DALTON TRANSACTIONS,2007 ,(38):4252-4254 |
| Palavras-Chave | #EARTH-METAL COMPLEXES #OLEFIN POLYMERIZATION #ALKYL COMPLEXES #CATALYSIS #YTTRIUM #REACTIVITY #CHEMISTRY #COPOLYMERIZATION #PALLADIUM(II) #ISOPRENE |
| Tipo |
期刊论文 |
