Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit
Data(s) |
2009
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Resumo |
Four transition-metal-amine complexes incorporating indium thioarsenates with the general formula M(tren)InAsS4 (M=Mn, Co, and Zn) and a noncondensed AsS33- unit have been prepared and characterized. Single-crystal X-ray diffraction analyses show that compound 1 (M=Mn) crystallizes in the triclinic crystal system (space group: P (1) over bar) and consists of a one-dimensional (1D) inorganic (1)(infinity){[InAsS4](2-)} chain and [Mn(tren)](2+) groups bonded to the opposite sides of an eight-membered In2As2S4 ring along the backbone of the infinite inorganic chains. Compounds 2 (M=Mn), 3 (M=Zn), and 4 (M=Co) are isomorphous molecular compounds. They all crystallize in the monoclinic crystal system (space group: P2(1)/c). The Mn2+ cation of [Mn(tren)](2+) in 1 has a distorted octahedral environment, while the transition-metal cations of [M(tren)](2+) in the other three compounds locate in trigonal-bipyramidal environments. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Wang ZQ;Zhang HJ;Wang C.Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit,INORGANIC CHEMISTRY ,2009,48 (17 ):8180-8185 |
Palavras-Chave | #TRANSITION-METAL-COMPLEXES #SOLVOTHERMAL SYNTHESIS #CRYSTAL-STRUCTURES #SOLID-STATE #SOLVENTOTHERMAL SYNTHESIS #HYDROTHERMAL SYNTHESIS #CHALCOGENIDE CLUSTERS #COORDINATION POLYMERS #INDIUM SULFIDES #EXTENDED CHAINS |
Tipo |
期刊论文 |