Stabilization of Imidosamarium(III) Cubane by Amidinates
| Data(s) |
2009
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|---|---|
| Resumo |
An imidosamarium(III) cubane has been prepared from the reductive cleavage of azobenzene by a divalent samarium bis (amidinate) complex, indicating that the "spectratoe" bis(amidinate) and the resulting imido ligands help to stabilize the cubane framework. The cubane-type imido cluster is a novel unit in lanthanide chemistry. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Pan CL;Chen W;Song SY;Zhang HJ;Li XW.Stabilization of Imidosamarium(III) Cubane by Amidinates,INORGANIC CHEMISTRY,2009,48(14):6344-6346 |
| Palavras-Chave | #DIVALENT LANTHANIDE COMPLEXES #IRON-SULFUR CLUSTERS #STRUCTURAL-CHARACTERIZATION #DINITROGEN REDUCTION #IMIDO COMPLEXES #ORGANOLANTHANIDE CHEMISTRY #ORGANOMETALLIC COMPOUNDS #MOLECULAR-STRUCTURE #SAMARIUM #METAL |
| Tipo |
期刊论文 |
