Synthesis of Liquid Polybutadiene Having Desired 1,2-Vinyl Content with Co(naph)(2)-Al-2(C2H5)(3)Cl-3-P(OPh)(3) Catalyst System


Autoria(s): Hao XF; Zhang CY; Cai HG; Jiang LS; Na LH; Bi JF; Yu QZ; Dai QQ; Zhang ML; Zhang XQ
Data(s)

2009

Resumo

Liquid polybutadiene with desirable 1,2-units content was synthesized by Co(naph)(2)-Al-2(C2H5)(3)Cl-3-P(OPh)(3) catalyst system. It was shown that liquid polybutadiene having adequate 1,2-unit content (vinvl =35%-40%) molecular weight(M-n = 700-3500), and acceptabele conversion(>= 55%) can synthesized after optimizing polymerization conditions.

Identificador

http://202.98.16.49/handle/322003/11303

http://www.irgrid.ac.cn/handle/1471x/147890

Idioma(s)

中文

Fonte

Hao XF;Zhang CY;Cai HG;Jiang LS;Na LH;Bi JF;Yu QZ;Dai QQ;Zhang ML;Zhang XQ.Synthesis of Liquid Polybutadiene Having Desired 1,2-Vinyl Content with Co(naph)(2)-Al-2(C2H5)(3)Cl-3-P(OPh)(3) Catalyst System,CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE ,2009,30(10):2082-2085

Tipo

期刊论文