[Ru(bpy)(3)](2+) nanocomposites containing heteropolyacids: Simple preparation and stable solid-state electrochemiluminescence detection application
Data(s) |
2009
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Resumo |
In order to solidify the electrochemiluminescence (ECL) luminophor tris(2,2'-bipyridyl) ruthenium(II) ([Ru(bpy)(3)](2+)) onto the electrode surfaces robustly, the negative charged heteropolyacids (HPAs) moieties were utilized to attract and bond cations [Ru(bpy)(3)](2+) via an adsorption method. The compositions and microstructures of the hybrid complexes were characterized by elemental analysis (EDS), spectroscopic techniques (UV-vis, FTIR) and field-emission scanning electron microscopy (FE-SEM). The electrochemical and ECL behaviors of the [Ru(bpy)(3)](2+)/[PW12O40](3-) hybrid complex contained in the solid film of the nanocomposites formed on the electrode surfaces were also studied. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Li YL;Zhu H;Yang XR.[Ru(bpy)(3)](2+) nanocomposites containing heteropolyacids: Simple preparation and stable solid-state electrochemiluminescence detection application,TALANTA ,2009,80(2 ):870-874 |
Palavras-Chave | #ELECTROGENERATED CHEMILUMINESCENCE #TUNGSTOPHOSPHORIC ACID #ELECTRODE #FILM #RU(BPY)(3)(2+) #MEMBRANES #RUTHENIUM #SYSTEM |
Tipo |
期刊论文 |