The optical properties and the natural lifetime calculation of a Sm(III) complex
Data(s) |
2008
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Resumo |
The photophysical properties of the complex Sm(PM)(3)(TP)(2) [PM = 1-phenyl-3-methyl-4-isobutyryl-5-pyrazolone, TP = triphenyl phosphine oxide] are determined in crystal state, and energy transfer process is modeled for ligands to center Sm(III) ion. The characteristic luminescence of Sm(III) is sensitized by PM and TP, and most of transitions from excited state (4)G(5/2) of Sm3+ are detected. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Li ZF;Yu JB;Zhou LA;Zhang HJ;Deng RP.The optical properties and the natural lifetime calculation of a Sm(III) complex,INORGANIC CHEMISTRY COMMUNICATIONS,2008,11(10):1284-1287 |
Palavras-Chave | #INTRAMOLECULAR ENERGY TRANSFER #EXCITED-STATE DYNAMICS #RARE-EARTH IONS #LANTHANIDE IONS #LUMINESCENCE #CRYSTAL #SPECTRA #INTENSITIES #ABSORPTION #ND3+ |
Tipo |
期刊论文 |