New chiral ferrocenyldiphosphine ligand for catalytic asymmetric transfer hydrogenation
| Data(s) |
16/02/2004
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| Resumo |
New chiral ferrocenyldiphosphine ligands (R)-(S)-3 and (R)-(S)-4 were prepared. The ligands were employed in Ru(II) catalyzed asymmetric transfer hydrogenation of ketones to give corresponding secondary alcohols. Up to 99% conversion with 90% e.e. was obtained on Ru(DMSO)(4)Cl-2/4 in transfer hydrogenation of acetophenones with propan-2-ol. (C) 2003 Elsevier B.V. All rights reserved. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
戴慧聪;胡向平;陈惠麟;白长敏;郑卓.New chiral ferrocenyldiphosphine ligand for catalytic asymmetric transfer hydrogenation,Journal of Molecular Cataylsis A:Chemical,2004,209():19-22 |
| Palavras-Chave | #ferrocenyldiphosphine #transfer hydrogenation #(R)-N-(2-(diphenylphosphino)benzylidene)-1-((S)-2-(diphenylphosphino)ferrocenyl)ethylamine |
| Tipo |
期刊论文 |
