TCNQ脂类衍生物及其铜复合物的合成与红外光谱研究


Autoria(s): 黄伍桥; 吴谊群; 顾冬红; 干福熹
Data(s)

2005

Resumo

首次合成了7,7,8,8-四氰基对苯醌二甲烷的脂类衍生物:TCNQ(C2H4COOR)2(R=CH3,C2H5,C3H7)及其铜电子转移复合物。通过元素分析确定这些化合物的组成,对这些化合成物在4000~400cm^-1范围内的主要红外光谱吸收峰进行了归属,并讨论了取代基对TCNQ类衍生物红外光谱的影响及其规律。

Three ester derivatives of tetracyanoquinodimethane and their CT complexes were synthesized and characterized by elementary analysis and infrared spectra. The principal infrared absorption peaks were assigned and discussed for the region of 4 000-400 cm(-1). Principal factors affecting principal infrared absorption were analyzed.

Identificador

http://ir.siom.ac.cn/handle/181231/3887

http://www.irgrid.ac.cn/handle/1471x/11323

Idioma(s)

中文

Fonte

黄伍桥;吴谊群;顾冬红;干福熹.TCNQ脂类衍生物及其铜复合物的合成与红外光谱研究,光谱学与光谱分析,2005,25(10):1577-1580

Palavras-Chave #光存储 #TCNQ脂类衍生物 #电子转移复合物 #红外光谱 #ester derivatives of TCNQ #charge-transfer complex #IR spectrum
Tipo

期刊论文