Solid state structure of p-bromo phenyl 4,5,7-tri-O-benzyl-beta-D-glycero-D-talo-septanoside and an analysis of non-covalent interactions
Data(s) |
2015
|
---|---|
Resumo |
The solid state structure of a new seven-membered sugar oxepane derivative, namely, p-bromo phenyl 4,5,7-tri-O-benzyl-beta-D-glycero-D-talo-septanoside is discussed, as determined through single crystal X-ray structural determination and in relation to their conformational features. The molecule adopts twist-chair as the preferred conformation, with conformational descriptor (TC2,3)-T-0,1. The solid state packing of molecules is governed by a rich network of non-covalent bonding originating from O-H center dot center dot center dot O, C-H center dot center dot center dot pi, C-H center dot center dot center dot Br and aromatic pi center dot center dot center dot pi interactions that stabilize the packing of molecules in the crystal. (C) 2015 Elsevier Ltd. All rights reserved. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/51758/1/Car_hyd_res_410_9_2015.pdf Dey, Supriya and Basuroy, Krishnayan and Jayaraman, N (2015) Solid state structure of p-bromo phenyl 4,5,7-tri-O-benzyl-beta-D-glycero-D-talo-septanoside and an analysis of non-covalent interactions. In: CARBOHYDRATE RESEARCH, 410 . pp. 9-14. |
Publicador |
ELSEVIER SCI LTD |
Relação |
http://dx.doi.org/ 10.1016/j.carres.2015.03.020 http://eprints.iisc.ernet.in/51758/ |
Palavras-Chave | #Molecular Biophysics Unit #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |