Observation of a reversible isomorphous phase transition and an interplay of ``sigma-holes'' and ``pi-holes'' in Fmoc-Leu-psiCH2-NCS]
| Data(s) |
2015
|
|---|---|
| Resumo |
Fmoc-Leu-psiCH2NCS] undergoes a reversible isomorphous phase transition upon cooling. The crystal structure at 100 K displays a short N=C=S center dot center dot center dot N=C=S intermolecular interaction, which has been characterized based on experimental charge density analysis, as a stabilizing interaction with both sigma-holes and pi-holes acting cooperatively. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/50706/1/che_comm_51-5_933_2015.pdf Pal, Rumpa and Nagendra, Govindappa and Samarasimhareddy, M and Sureshbabu, Vommina V and Row, Tayur Guru N (2015) Observation of a reversible isomorphous phase transition and an interplay of ``sigma-holes'' and ``pi-holes'' in Fmoc-Leu-psiCH2-NCS]. In: CHEMICAL COMMUNICATIONS, 51 (5). pp. 933-936. |
| Publicador |
ROYAL SOC CHEMISTRY |
| Relação |
http://dx.doi.org/ 10.1039/c4cc08751h http://eprints.iisc.ernet.in/50706/ |
| Palavras-Chave | #Solid State & Structural Chemistry Unit |
| Tipo |
Journal Article PeerReviewed |
