Photoluminescence properties of Eu3+-activated CaMoO4 phosphors for WLEDs applications and its Judd-Ofelt analysis
Data(s) |
2015
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Resumo |
A series of scheelite-type Eu3+-activated CaMoO4 phosphors were synthesized by the nitrate-citrate gel combustion method. All the compounds crystallized in the tetragonal structure with space group I4(1)/a (No. 88). FESEM results reveal the spherical-like morphology. The CaMoO4 phosphor exhibited broad emission centered at 500 nm under the excitation of 298 nm wavelength, while Eu3+-activated CaMoO4 shows an intense characteristic red emission peak at 615 nm at different excitation wavelengths, due to D-5(0) -> F-7(2) transition of Eu3+ ions. The intensities of transitions between different J levels depend on the symmetry of the local environment of Eu3+ ions and were estimated using the Judd-Ofelt analysis. The high asymmetric ratio revealed that Eu3+ occupies sites with a low symmetry and without an inversion center. The CIE chromaticity co-ordinates (x, y) were calculated from emission spectra, and the values were close to the NTSC standard. Therefore, the present phosphor is highly useful for LEDs applications. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/50504/1/jou_mat_sci_50-1_287_2015.pdf Saraf, Rohit and Shivakumara, C and Dhananjaya, N and Behera, Sukanti and Nagabhushana, H (2015) Photoluminescence properties of Eu3+-activated CaMoO4 phosphors for WLEDs applications and its Judd-Ofelt analysis. In: JOURNAL OF MATERIALS SCIENCE, 50 (1). pp. 287-298. |
Publicador |
SPRINGER |
Relação |
http://dx.doi.org/ 10.1007/s10853-014-8587-3 http://eprints.iisc.ernet.in/50504/ |
Palavras-Chave | #Solid State & Structural Chemistry Unit |
Tipo |
Journal Article PeerReviewed |