Stabilization of Co-3 - Oxoclusters in a pcu Net: Synthesis, Structure, Solvent Exchange (Single Crystal to Single Crystal) and Magnetic Studies
Data(s) |
2014
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Resumo |
The solvothermal reaction of CoCl(2)4H(2)O and 4,4-sulfonyldibenzoic acid (H(2)SDBA) resulted in the formation of a three-dimensional coordination polymer Co-3(C14H8O6S)(3)(DMA)(2)(MeOH)].DMA (Ia) consisting of trinuclear Co-3 oxo-cluster units. The Co-3 trimeric units are connected by SDBA(2-) anions leading to a three dimensional structure with a pcu topology. The terminal methanol molecules could be exchanged in a single crystal to single crystal (SCSC) fashion by other similar solvent molecules (ethanol, acetonitrile, water, ethyleneglycol). Magnetic studies on the parent compound, Ia, indicate antiferromagnetic interactions between the central metal atoms. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/50479/1/zei_ano_all_che_640-14_2922_2014.pdf Bhattacharya, Saurav and Natarajan, Srinivasan (2014) Stabilization of Co-3 - Oxoclusters in a pcu Net: Synthesis, Structure, Solvent Exchange (Single Crystal to Single Crystal) and Magnetic Studies. In: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 640 (14, SI). pp. 2922-2930. |
Publicador |
WILEY-V C H VERLAG GMBH |
Relação |
http://dx.doi.org/ 10.1002/zaac.201400388 http://eprints.iisc.ernet.in/50479/ |
Palavras-Chave | #Solid State & Structural Chemistry Unit |
Tipo |
Journal Article PeerReviewed |