An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes
Data(s) |
2014
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Resumo |
A novel ring contraction/rearrangement sequence leading to functionalized 2,8-oxymethano-bridged di- and triquinane compounds is observed in the reaction of various substituted 1-methyl-4-isopropenyl-6-oxabicylo3.2.1]octan-8-ones with Lewis acids. The reaction is novel and is unprecedented for the synthesis of di- and triquinane frameworks. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/50443/1/ang_ahe_int_edi_53-41_10997_2014.pdf Nagaraju, Chinta and Prasad, Kavirayani R (2014) An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes. In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53 (41). pp. 10997-11000. |
Relação |
http://dx.doi.org/ 10.1002/anie.201407680 http://eprints.iisc.ernet.in/50443/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |