Regioselective Thiolation of Arenes and Heteroarenes: C-H Functionalization Strategy for C-S Bond Formation
Data(s) |
2014
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Resumo |
A facile transition-metal-free oxidative cross-dehydrogenative coupling reaction involving selective formation of a C-S bond leading to the synthesis of arylthiobenzoxazoles, heteroarylthiobenzoxazoles, and arylthiobenzothiazoles has been described. This highly regioselective C-H functionalization reaction with electron-rich aromatic systems including heteroaromatics is achieved by reversing the reactivity of sulfur in the presence of a suitable oxidant and strong acid. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/50328/1/jou_org_che_79-20_9655_2014.pdf Varun, Begur Vasanthkumar and Prabhu, Kandikere Ramaiah (2014) Regioselective Thiolation of Arenes and Heteroarenes: C-H Functionalization Strategy for C-S Bond Formation. In: JOURNAL OF ORGANIC CHEMISTRY, 79 (20). pp. 9655-9668. |
Publicador |
AMER CHEMICAL SOC |
Relação |
http://dx.doi.org/ 10.1021/joS01793q http://eprints.iisc.ernet.in/50328/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |