Role of Crosslinking and Entanglements in the Mechanics of Silicone Networks


Autoria(s): Babu, AR; Gundiah, N
Data(s)

2014

Resumo

The goal of this study is to investigate the applicability of different constitutive models for silicone networks using comprehensive multiaxial experimental tests, including non-equibiaxial mechanical tests which introduce differential constraints on the networks in the two orthogonal directions, on samples prepared using various crosslinking densities. Uniaxial stress-strain experiments show that a decrease in crosslinker amounts used in the preparation of silicone networks lead to more compliant material response as compared to that obtained using higher amounts of crosslinker. Biaxial data were used to obtain fits to the neo- Hookean, Mooney-Rivlin, Arruda-Boyce and the Edward-Vilgis slip-link constitutive models. Our results show that the slip-link model, based on separation of the individual contributions of chemical crosslinks and physical entanglements, is better at describing the stress-strain response of highly crosslinked networks at low stretches as compared to other constitutive models. Modulus obtained using the slip-link model for highly crosslinked networks agrees with experimentally determined values obtained using uniaxial tension experiments. In contrast, moduli obtained using coefficients to the other constitutive models underpredict experimentally determined moduli by over 40 %. However, the slip-link model did not predict the experimentally observed stiffening response at higher stretches which was better captured using the Arruda-Boyce model.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/49886/1/exp_mec_54-7_1177_2014.pdf

Babu, AR and Gundiah, N (2014) Role of Crosslinking and Entanglements in the Mechanics of Silicone Networks. In: EXPERIMENTAL MECHANICS, 54 (7). pp. 1177-1187.

Relação

http://dx.doi.org/ 10.1007/s11340-014-9895-x

http://eprints.iisc.ernet.in/49886/

Palavras-Chave #Mechanical Engineering #Materials Engineering (formerly Metallurgy) #Centre for Nano Science and Engineering
Tipo

Journal Article

PeerReviewed