Enantiospecific Total Synthesis of Macrolactone Sch 725674
| Data(s) |
2014
|
|---|---|
| Resumo |
The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley's dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/49766/1/org_let_16-15_4001_2014.pdf Bali, Amit K and Sunnam, Sunil K and Prasad, Kavirayani R (2014) Enantiospecific Total Synthesis of Macrolactone Sch 725674. In: ORGANIC LETTERS, 16 (15). pp. 4001-4003. |
| Publicador |
AMER CHEMICAL SOC |
| Relação |
http://dx.doi.org/ 10.1021/ol5018678 http://eprints.iisc.ernet.in/49766/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
