Mechanistic studies on the diazo transfer reaction


Autoria(s): Pandiakumar, Arun Kumar; Sarma, Siddhartha P; Samuelson, Ashoka G
Data(s)

2014

Resumo

The mechanism of the diazo transfer reaction which converts amines to azides has been studied with labeled amino acids and labeled imidazole-l-sulfonyl azides. Retention of amine nitrogen in the amine, and transfer of the two terminal nitrogen atoms of the imidazole-l-sulfonyl azide to the product, were unambiguously established. (C) 2014 Elsevier Ltd. All rights reserved.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/49256/1/tet_let_55-18_2917_2014.pdf

Pandiakumar, Arun Kumar and Sarma, Siddhartha P and Samuelson, Ashoka G (2014) Mechanistic studies on the diazo transfer reaction. In: TETRAHEDRON LETTERS, 55 (18). pp. 2917-2920.

Publicador

PERGAMON-ELSEVIER SCIENCE LTD

Relação

http://dx.doi.org/10.1016/j.tetlet.2014.03.057

http://eprints.iisc.ernet.in/49256/

Palavras-Chave #Molecular Biophysics Unit #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed