Triarylborane-Appended New Triad and Tetrad: Chromogenic and Fluorogenic Anion Recognition
Data(s) |
2014
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Resumo |
Facile synthesis of triad 3 and tetrad 4 incorporating -B(Mes)(2) (Mes = mesityl (2,4,6-trimethylphenyl)), boron dipyrromethene (BODIPY), and triphenylamine is reported. Introduction of two dissimilar acceptors (triarylborane and BODIPY) on a single donor resulted in two distinct intramolecular charge transfer processes (amine-to-borane and amine-to-BODIPY). The absorption and emission properties of the new triad and tetrad are highly dependent on individual building units. The nature of electronic communication among the individual fluorophore units has been comprehensively investigated and compared with building units. Compounds 3 and 4 showed chromogenic and fluorogenic responses for small anions such as fluoride and cyanide. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/48978/1/ino_che_53-6_2776_2014.pdf Swamy, Chinna Ayya P and Thilagar, Pakkirisamy (2014) Triarylborane-Appended New Triad and Tetrad: Chromogenic and Fluorogenic Anion Recognition. In: INORGANIC CHEMISTRY, 53 (6). pp. 2776-2786. |
Publicador |
AMER CHEMICAL SOC |
Relação |
http://dx.doi.org/10.1021/ic402898n http://eprints.iisc.ernet.in/48978/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |