Ring opening of activated cyclopropanes with NIS/NaN3: synthesis of C-1 linked pseudodisaccharides


Autoria(s): Haveli, Shrutisagar Dattatraya; Roy, Sudipta; Gautam, Vibha; Parmar, Ketan C; Chandrasekaran, Srinivasan
Data(s)

2013

Resumo

NIS/NaN3 mediated ring opening of various donor-acceptor cyclopropanes has been investigated. The study shows the necessity of the donor oxygen lone pair in such ring opening reactions. This methodology has been utilized in the synthesis of C-1 linked pseudodisaccharides through the use of click chemistry. (C) 2013 Elsevier Ltd. All rights reserved.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/48376/1/Tet_69-52_11138_2013.pdf

Haveli, Shrutisagar Dattatraya and Roy, Sudipta and Gautam, Vibha and Parmar, Ketan C and Chandrasekaran, Srinivasan (2013) Ring opening of activated cyclopropanes with NIS/NaN3: synthesis of C-1 linked pseudodisaccharides. In: TETRAHEDRON, 69 (52). pp. 11138-11143.

Publicador

PERGAMON-ELSEVIER SCIENCE LTD

Relação

http://dx.doi.org/10.1016/j.tet.2013.11.005

http://eprints.iisc.ernet.in/48376/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed