Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation
| Data(s) |
2014
|
|---|---|
| Resumo |
An enantioselective desymmetrization of prochiral 1,3-dinitropropanes has been developed which proceeds via enantiogroup differentiating organocatalytic allylic alkylation. Densely functionalized products with two vicinal stereocenters were obtained generally with good to excellent diastereoselectivity (up to >20:1 dr) and superb enantioselectivity (up to >99:1 er). |
| Formato |
application/pdf application/pdf application/pdf text/plain |
| Identificador |
http://eprints.iisc.ernet.in/48043/1/Che_Com_50-1_121_2014.pdf http://eprints.iisc.ernet.in/48043/2/Che_com_121_2014_A.pdf.pdf http://eprints.iisc.ernet.in/48043/3/Che_Com_121_2014_B_2014.pdf http://eprints.iisc.ernet.in/48043/19/c3cc47645f.txt Roy, Soumya Jyoti Singha and Mukherjee, Santanu (2014) Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation. In: CHEMICAL COMMUNICATIONS, 50 (1). pp. 121-123. |
| Publicador |
ROYAL SOC CHEMISTRY |
| Relação |
http://dx.doi.org/10.1039/c3cc47645f http://eprints.iisc.ernet.in/48043/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
