Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion


Autoria(s): Balaji, Pandur Venkatesan; Chandrasekaran, Srinivasan
Data(s)

2014

Resumo

An anti-Markovnikov geminal oxyamination of styrenyl alkenes in an intermolecular fashion using the umpolung strategy mediated by the bromonium ion is reported. Isotope labeling studies confirm the migration of the phenyl group in the semipinacol rearrangement.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/48042/1/Che_Com_50-1_70_2014.pdf

Balaji, Pandur Venkatesan and Chandrasekaran, Srinivasan (2014) Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ion. In: CHEMICAL COMMUNICATIONS, 50 (1). pp. 70-72.

Publicador

ROYAL SOC CHEMISTRY

Relação

http://dx.doi.org/10.1039/c3cc46003g

http://eprints.iisc.ernet.in/48042/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed