A new 3D cadmium(II) coordination polymer having mu(4)-oxalato, mu-aquo and mu-chlorido bridges: crystal structure, solid state fluorescence and thermal behavior


Autoria(s): Dey, Subrata K; Shit, Shyamapada; Sankolli, Ravish; Row, Guru Tayur N
Data(s)

24/09/2013

Resumo

A new 3D cadmium(II) coordination polymer, Cd(C2O4)(0.5)Cl(H2O)](n) (1) has been synthesized from a mixture of CdCl2. H2O and (NH4)(2)C2O4 in a slightly acidic pH. Its molecular structure was determined by single crystal X-ray diffraction which reveals that the new polymeric structure consists of simultaneous mu(4)-oxalato, mu-aquo, and mu-chlorido bridges between the metal centers, embedded in distorted pentagonal bipyramidal geometries. On thermal analysis compound exhibits high thermal stability up to 330 degrees C. Compound 1 also exhibits strong fluorescent emission. (c) 2013 Elsevier B.V. All rights reserved.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/47418/1/Jour_Mole_Stru_1048_6_2013.pdf

Dey, Subrata K and Shit, Shyamapada and Sankolli, Ravish and Row, Guru Tayur N (2013) A new 3D cadmium(II) coordination polymer having mu(4)-oxalato, mu-aquo and mu-chlorido bridges: crystal structure, solid state fluorescence and thermal behavior. In: Journal of Molecular Structure, 1048 . pp. 6-10.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/j.molstruc.2013.05.018

http://eprints.iisc.ernet.in/47418/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed